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Atmospheric water harvesting (AWH) has been extensively researched as a sustainable solution to current freshwater scarcity. Various bioinspired AWH surfaces have been developed to enhance water-harvesting performance, yet challenges remain in optimizing their structures. In this work, we report a dual-biomimetic AWH surface that combines beetle-inspired heterogeneous wettability with leaf-skeleton-based hierarchical microstructures on a rigid substrate. An authentic leaf skeleton innovatively serves as the mask during photolithography complemented by O2-plasma treatment, enabling precise design of superhydrophilic SiO2 structures with a hierarchy of vein orders forming reticulate meshes on a hydrophobic Si substrate. This design facilitates enhanced water collection through intricate reticulate meshes and directional droplet transport along the abundant multi-order veins. Such AWH surface shows a water-harvesting efficiency of 172 mg cm−2 h−1, increasing up to 62% and 58% over the pristine SiO2/Si wafer and Si wafer, respectively. Additionally, the role of structure orientation in the open-surface droplet transport is explored while the AWH surface is vertically placed during the water-harvesting process. This work highlights the potential of using meticulous natural designs, like leaf skeletons, to improve AWH surfaces, with broad applications in compact devices, such as on-chip evaporative cooling and planar microfluidics manipulation.more » « lessFree, publicly-accessible full text available January 6, 2026
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Heat exchange between a solid material and the gas environment is critical for the heat dissipation of miniature electronic devices. In this aspect, existing experimental studies focus on non-porous structures such as solid thin films, nanotubes, and wires. In this work, the proposed two-layer model for the heat transfer coefficient (HTC) between a solid sample and the surrounding air is extended to 70-nm-thick nanoporous Si thin films that are patterned with periodic rectangular nanopores having feature sizes of 100–400 nm. The HTC values are extracted using the 3[Formula: see text] method based on AC self-heating of a suspended sample with better accuracy than steady-state measurements in some studies. The dominance of air conduction in the measured HTCs is confirmed by comparing measurements with varied sample orientations. The two-layer model, developed for nanotubes, is still found to be accurate when the nanoporous film is simply treated as a solid film in the HTC evaluation along with the radiative mean beam length as the characteristic length of the nanoporous film. This finding indicates the potential of increasing HTC by introducing ultra-fine nanoporous patterns, as guided by the two-layer model.more » « less
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null (Ed.)Abstract. Local spatiotemporal nonstationarity occurs in various naturaland socioeconomic processes. Many studies have attempted to introduce timeas a new dimension into a geographically weighted regression (GWR) model,but the actual results are sometimes not satisfying or even worse than theoriginal GWR model. The core issue here is a mechanism for weighting the effectsof both temporal variation and spatial variation. In many geographical andtemporal weighted regression (GTWR) models, the concept of time distance hasbeen inappropriately treated as a time interval. Consequently, the combinedeffect of temporal and spatial variation is often inaccurate in theresulting spatiotemporal kernel function. This limitation restricts theconfiguration and performance of spatiotemporal weights in many existingGTWR models. To address this issue, we propose a new spatiotemporal weightedregression (STWR) model and the calibration method for it. A highlight ofSTWR is a new temporal kernel function, wherein the method for temporalweighting is based on the degree of impact from each observed point to aregression point. The degree of impact, in turn, is based on the rate ofvalue variation of the nearby observed point during the time interval. Theupdated spatiotemporal kernel function is based on a weighted combination ofthe temporal kernel with a commonly used spatial kernel (Gaussian orbi-square) by specifying a linear function of spatial bandwidth versus time.Three simulated datasets of spatiotemporal processes were used to test theperformance of GWR, GTWR, and STWR. Results show that STWR significantlyimproves the quality of fit and accuracy. Similar results were obtained byusing real-world data for precipitation hydrogen isotopes (δ2H) in the northeastern United States. The leave-one-out cross-validation(LOOCV) test demonstrates that, compared with GWR, the total predictionerror of STWR is reduced by using recent observed points. Predictionsurfaces of models in this case study show that STWR is more localized thanGWR. Our research validates the ability of STWR to take full advantage ofall the value variation of past observed points. We hope STWR can bringfresh ideas and new capabilities for analyzing and interpreting localspatiotemporal nonstationarity in many disciplines.more » « less
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